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In geology, a vein is a finite volume within a rock, having a distinct shape, filled with crystals of one or more minerals, which were precipitated from an (aqueous) fluid. Veins are formed by fluids carrying mineral constituents into a rock mass as a consequence of some form of hydraulic flow within the rock. Usually this is the result of hydrothermal circulation.

Veins are classically thought of as being the result of growth of crystals on the walls of planar fractures in rocks, with the crystal growth occurring normal to the walls of the cavity, and the crystal protruding into open space.

This certainly is the method for the formation of some veins. However, it is rare in geology for significant open space to remain open in large volumes of rock, especially several kilometers below the surface. Thus, there are two main mechanisms considered likely for the formation of veins open-space filling and crack-seal growth.

Open space filling is the hallmark of epithermal vein systems, such as a stockwork, in greisens or in certain skarn environments. For open space filling to take effect, the confining pressure is generally considered to be below 0.5 GPa, or less than 3-5 kilometres. Veins formed in this way may exhibit a colloform, agate-like habit, of sequential selvedges of minerals which radiate out from nucleation points on the vein walls and appear to fill up the available open space. Often evidence of fluid boiling is present. Vugs, cavities and geodes are all examples of open-space filling phenomenon in hydrothermal systems.

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